The surface finish obtained by electropolishing is primarily a function
of the surface quality and finish before processing. Brighter finishes are
obtained be increasing time, temperature, and/or current density, which
also increases metal removal from high current density areas. This must
be considered when dimensions are of critical tolerance.
During the process hydrogen is liberated from the cathode, and
oxygen from the anode. This causes a partial passivation of the surface
and improved corrosion resistance by leaving a transparent chromium
oxide film on the surface but, unlike plating, the problem of hydrogen
embrittlement is nonexistent. A complete passivation, if needed, must
be performed as an added processing step after electropolishing.
Surface brightness (anodic luster), accomplished through
electropolishing, is different from that produced abrasively or mechanically
It is scratch-free, deformation-free and directionless, and the true metal
color is revealed. Contrary to popular belief surface brightness is not
always a true measure of surface smoothness.
The surface finish, in micro-inches, is usually reduced from 33 to 66
percent. However, as the valises become lower prior to the process,
the improvement percentage decreases proportionally. The greatest
contributing factors toward poor results are large grain size,
non-uniform structure, noncompatible inclusions, directional roll marks,
salt or scale contaminations, and wide variations in beginning surface
conditions. Fine grained deposits are most important for tree reflective
finishes.